NOVEL THINKING

In contact with mucous membranes, hydrolysis produces hydrochloric acid. Propylene oxide is sometimes added as inhibitor, at concentrations between 0.25-1%.

Editor's note: Some chemicals in this database contain more information than others due to the original reason this information was collected and how the compilation was accomplished. The distilled benzyl chloride contains some water, which can be removed by using molecular sieves or some other drying agent.[1]. All rights reserved. Benzyl ethers are often derived from benzyl chloride. There are several routes to benzyl chloride: The most common route involves refluxing benzyl alcohol with an excess of fuming conc. More info.

HTML 5 canvas support. It is classified as an extremely hazardous substance in the United States as defined in Section 302 of the U.S. Eng. This IR spectrum is from the

Use online or print pages out as classroom handouts. Introduces stoichiometry and explains the differences between molarity, molality and normality. Chemical Database - Benzyl Chloride. Empirical Formula (Hill Notation): C33H39ClN2O2. Khim., 37(2), 2001, 283-293, In original 283-293. ass: Standard non-polar; Column type: Capillary; CAS no: 100447; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Zenkevich, I.G., Mutual Correlation between Gas-Chromatographic Retention Indices of Organic Compounds from Different Series, Zh. The more common, regulated and/or hazardous a chemical is, the more information I will have likely collected it.

Hazardous materials placards (DOT placards) are required when shipping hazardous materials in the United States, Canada and Mexico. To resolve this problem, over the years, I compiled chemical names and identifiers into a personal database, cross referencing regulatory and health safety information when possible. umn class: Standard non-polar; Column length: 3 m; Column type: Packed; Start T: 150 C; CAS no: 100447; Active phase: SE-30; Carrier gas: Ar; Substrate: Gas Chrom Q (80-100 mesh); Data type: Kovats RI; Authors: Tiess, D., Gaschromatographische Retentionsindices von 125 leicht- bis mittelfluchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30, Wiss. Benzyl chloride, or α-chlorotoluene, is an organic compound with the formula C6H5CH2Cl. C19H34ClN. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), NIST Mass Spectrometry Data Center, William E. Wallace, director, Modified by NIST for use in this application.

; Gutch, P.K., Gas chromatographic retention indices of tear gases on capillary columns, J. Synonym: N,N-Dimethyl-N- [4- [ [ [2- (4-methylphenyl)-6,7-dihydro-5H-benzohepten-8-yl]carbonyl]amino]benzyl]tetrahydro-2H-pyran-4-aminium chloride, TAK-799, Takeda 779.

Benzyltributylammonium chloride. Indicative of its high reactivity (relative to alkyl chlorides), benzyl chloride reacts with water in a hydrolysis reaction to form benzyl alcohol and hydrochloric acid. Shake the funnel to properly neutralize the acid from the layer. Prairie Dog Control: Non-Lethal Techniques. Benzyl chloride, or α-chlorotoluene, is an organic compound with the formula C6H5CH2Cl. Have you ever wondered what those four digit numbers on the placards on the side of trucks and rail cars mean? However, NIST makes no warranties to that effect, and NIST Site Use Terms Org. Benzyl chloride (other names - benzyl chloride, chloromethyl benzene, alpha-chlorotoluene) is an organochlorine compound, a derivative of benzene. Benzoic acid (C6H5COOH) can be prepared by oxidation of benzyl chloride in the presence of alkaline KMnO4: Benzyl chloride may be used in the synthesis of amphetamine-class drugs, and for this reason, sales of benzyl chloride are monitored as a List II drug precursor chemical by the US Drug Enforcement Administration. If you would like to link to this page from your website, blog, etc., copy and paste this link code (in red) and modify it to suit your needs: echo Chemical Database: Benzyl Chloride (EnvironmentalChemistry.com)- This page contains information on the chemical Benzyl Chloride including: 27 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information.. Benzyl chloride is an alkylating agent. Alternatively, an alcoholic solution of NaOH or KOH can be used. uses its best efforts to deliver a high quality copy of the 100-44-7 - KCXMKQUNVWSEMD-UHFFFAOYSA-N - Benzyl chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information. benzyl chloride 100-44-7 MSDS report, benzyl chloride MSDS safety technical specifications search, benzyl chloride safety information specifications ect. All Rights Reserved.

; Brinkman, U.A.Th., Unravelling the composition of very complex samples by comprehensive gas chromatography coupled to time-of-flight mass spectrometry. The purpose of the fee is to recover costs associated This site and the author do not warrant or guarantee the accuracy or the sufficiency of the information provided and do not assume any responsibility for its use.

Accessed on-line: 11/12/2020https://EnvironmentalChemistry.com/yogi/chemicals/cn/Benzyl%A0Chloride.html. It is not uncommon for wide range of molar ratios of a mixture to be lumped together as "synonyms" of the same "chemical". Looking Good, Feeling Bad; or, What's the Problem with Perc? Z. Wilhelm-Pieck-Univ. Chromatogr., 479, 1989, 165-169. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2.5 K/min; Start T: 50 C; End T: 200 C; CAS no: 100447; Active phase: DB-5; Carrier gas: He; Phase thickness: 1 um; Data type: Linear RI; Authors: Dalluge, J.; van Stee, L.L.P. (7) The chemical formula for benzyl chloride is C 7 H 7 Cl, and it has a molecular weight of 126.59 g/mol. ; Heintz, A., Vapor pressures and entalpies of vaporization of benzyl halides and benzyl ethers, J. Chem. This colorless liquid is a reactive organochlorine compound that is a widely used chemical building block. ; Lee, D.W.; Heo, G.S., Determination of volatile organic compounds (VOCs) using tedlar bag/solid-phase microextraction/gas chromatography/mass spectrometry (SPME/GC/MS) in ambient and workplace air, Bull. These pages provide US DOT definitions for each hazmat placard. View image of digitized Sigma-Aldrich offers a number of Benzyl chloride products. The process releases heat and HCl. The sale of this compound is restricted or monitored, due to its use in the synthesis of amphetamine-class drugs. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) In some instances chemicals that are very similar from a health & safety and/or regulatory standpoint also may have been lumped together. Can Prairie Dogs be Managed Utilizing Reconciliation Ecology? For example, (C 6 H 5)(CH 3) 2 C + is referred to as a "benzylic" carbocation. SDS; CoA; CAS #: 100-44-7 Hill Formula: C₇H₇Cl Chemical Formula: C₆H₅CH₂Cl EC Number: 202-853-6 Molar Mass: 126.58 g/mol. shall not be liable for any damage that may result from In the chemical industry, it is used to replace benzyl groups in other substances. Light is needed to initiate the reaction, but once it starts, there's no need to further expose the flask to strong light, unless your goal is to continue the reaction. intended to imply recommendation or endorsement by the National

Molecular Formula C 7 H 7 Cl; Average mass 126.584 Da; Monoisotopic mass 126.023628 Da; ChemSpider ID 13840690 Some chemicals listed in this database or not pure chemical compounds, rather they are mixtures/solutions of chemicals. been selected on the basis of sound scientific judgment. The reaction proceeds by the free radical process, involving the intermediacy of free chlorine atoms. (e.g., Sadtler Research Labs Under US-EPA Contract. [6], InChI=1S/C7H7Cl/c8-6-7-4-2-1-3-5-7/h1-5H,6H2, InChI=1/C7H7Cl/c8-6-7-4-2-1-3-5-7/h1-5H,6H2, Except where otherwise noted, data are given for materials in their, Emergency Planning and Community Right-to-Know Act, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, "40 C.F.R.

Sorry we cannot compare more than 4 products at a time. Colorless to slightly yellow liquid with a pungent, aromatic odor. +86-400-6021-666 ; service@molbase.com; Sign in; Register; About Us; Chinese; Search Batch Search. Technology, Office of Data Benzyl chloride also reacts readily with metallic magnesium in water-free conditions, to produce a Grignard reagent, extremely useful for the synthesis of various compounds containing an aromatic ring. ], Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: No recommendation Provide: Eyewash, Quick drench, NIOSH REL : C 1 ppm (5 mg/m 3 ) [15-minute] OSHA PEL : TWA 1 ppm (5 mg/m 3 ). Notice: This spectrum may be better viewed with a Javascript ; Chupalov, A.A., New Possibilities of Chromato Mass Pectrometric Identification of Organic Compounds Using Increments of Gas Chromatographic Retention Indices of Molecular Structural Fragments, Zh. Provides comprehensive data for each element of the periodic table of elements including up to 40 properties, names in 10 languages and common chemical compounds. Produced by the US DOT the ERG is designed to aid first responders in quickly identifying specific or generic hazards of materials involved in an incident and protecting themselves and the general public during the initial response phase of an incident. We are a great educational resource! In this area is widely used. [5] It is preferable over benzyl bromide for the preparation of this reagent, since the reaction of the bromide with magnesium tends to form the Wurtz coupling product 1,2-diphenylethane. Data for this database was compiled from: hundreds of Material Safety Data Sheets (MSDS) of common industrial and household products; the Hazardous Materials Table from the United States "Code of Federal Regulations" title 49 section 172.101; the National Institute for Occupational Safety and Health Pocket Guide to Chemical Hazards; the US DOT 1996, 2000 & 2004 Emergency Response Guidebooks; U.S. National Library of Medicine and many other related resources.

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