NOVEL THINKING

Thank you so much. Shouldn’t CH3Cl be -2 and acetylene be -1? I know that there are RedOx reactions that are favored by acidity, but can you say that “oxidation is favored by acidity” (probably not?!)? Aldehydes and Ketones: 14 Reactions With The Same Mechanism, Carbonyl Chemistry: 10 Key Concepts (Part 1). Addition to Alkenes

These concepts have never made sense to me and learning ochem had made it harder. But if you go back to the concept of the oxidation state, it might make some more sense. Mechanism :: Alcohol Mechanism :: Hydroboration Mechanism :: Free Radical Halogenation Mechanism :: S N 2 ... Baeyer-Villager Oxidation . See how oxidation leads to removal of electrons, and reduction leads to a gain of electrons. J. N. Moorthy, K. N. Parida, J. Org.

The half reactions are: Oxidation half-reaction: Fe(s) → Fe2+(aq) + 2e-, Reduction half-reaction: O2(g) + 2H2O(l) + 4e- → 4HO-(aq). Start with a value of 0 for the carbon. Chem., 2014, 79, 11431-11439. So this would be for O, Cl, F, N, Br, etc.

The Heck, Suzuki, and Olefin Metathesis Reactions (And Why They Don't Belong In Most Introductory Organic Chemistry Courses), Reaction Map: Reactions of Organometallics, Degrees of Unsaturation (or IHD, Index of Hydrogen Deficiency), Conjugation And Color (+ How Bleach Works), UV-Vis Spectroscopy: Absorbance of Carbonyls, Bond Vibrations, Infrared Spectroscopy, and the "Ball and Spring" Model, Infrared Spectroscopy: A Quick Primer On Interpreting Spectra, Natural Product Isolation (1) - Extraction, Natural Product Isolation (2) - Purification Techniques, An Overview, Structure Determination Case Study: Deer Tarsal Gland Pheromone, Conjugation And Resonance In Organic Chemistry, Molecular Orbitals of The Allyl Cation, Allyl Radical, and Allyl Anion, Reactions of Dienes: 1,2 and 1,4 Addition, Cyclic Dienes and Dienophiles in the Diels-Alder Reaction, Stereochemistry of the Diels-Alder Reaction, Exo vs Endo Products In The Diels Alder: How To Tell Them Apart, HOMO and LUMO In the Diels Alder Reaction. 3 - Effective Nuclear Charge, From Gen Chem to Organic Chem, Pt. [EDIT: fixed, thank you for the comments!]. I am so glad you found it useful Sarah. (Feel free to use this yourself, however). This also happens to be the first definition of oxidation and reduction I first learned in high school. Mechanism :: Williamson Addition to Carbonyl Groups Order Elimination How To Determine Hybridization: A Shortcut, Sigma bonds come in six varieties: Pi bonds come in one, A Key Skill: How to Calculate Formal Charge, Partial Charges Give Clues About Electron Flow, The Four Intermolecular Forces and How They Affect Boiling Points, How To Use Electronegativity To Determine Electron Density (and why NOT to trust formal charge), How To Use Curved Arrows To Interchange Resonance Forms, Evaluating Resonance Forms (1) - The Rule of Least Charges, How To Find The Best Resonance Structure By Applying Electronegativity, Evaluating Resonance Structures With Negative Charges, Evaluating Resonance Structures With Positive Charge, In Summary: Evaluating Resonance Structures, Drawing Resonance Structures: 3 Common Mistakes To Avoid, How to apply electronegativity and resonance to understand reactivity, The Stronger The Acid, The Weaker The Conjugate Base, Walkthrough of Acid-Base Reactions (3) - Acidity Trends, Acid-Base Reactions: Introducing Ka and pKa, A Handy Rule of Thumb for Acid-Base Reactions, How Protonation and Deprotonation Affect Reactivity, Meet the (Most Important) Functional Groups, Condensed Formulas: Deciphering What the Brackets Mean, Hidden Hydrogens, Hidden Lone Pairs, Hidden Counterions, Primary, Secondary, Tertiary, Quaternary In Organic Chemistry, Branching, and Its Affect On Melting and Boiling Points, Common Mistakes: Drawing Tetrahedral Carbons, Common Mistakes in Organic Chemistry: Pentavalent Carbon, Table of Functional Group Priorities for Nomenclature, Organic Chemistry IUPAC Nomenclature Demystified With A Simple Puzzle Piece Approach, Staggered vs Eclipsed Conformations of Ethane, Newman Projection of Butane (and Gauche Conformation), Geometric Isomers In Small Rings: Cis And Trans Cycloalkanes, Calculation of Ring Strain In Cycloalkanes, Cycloalkanes - Ring Strain In Cyclopropane And Cyclobutane, Cyclohexane Chair Conformation: An Aerial Tour, How To Draw The Cyclohexane Chair Conformation, The Cyclohexane Chair Flip - Energy Diagram, Substituted Cyclohexanes - Axial vs Equatorial, Ranking The Bulkiness Of Substituents On Cyclohexanes: "A-Values". Mechanism :: Friedel-Crafts water in the atmosphere) and forms iron(III) oxides. Mechanism :: Electrophilic So here’s the same reaction. google_ad_width = 120;

Master Organic Chemistry LLC, 1831 12th Avenue South, #171, Nashville TN, USA 37203, © Copyright 2020, Master Organic Chemistry, Photo credit: http://sclowcountryoutdoors.blogspot.com/2011/02/iron-smelting-at-acba.html, Oxidation and Reduction in Organic Chemistry. An oxidation will result in a net decrease in the number of C-H bonds, or a net increase in the number of C-O bonds (or equivalent). Why Do Organic Chemists Use Kilocalories.

I think this speaks to the ‘formalism’ aspect of oxidation states. What are the rules or formula you used to determine this? 11 - The Second Law, From Gen Chem to Org Chem Pt. F. A. Davis, A. C. Sheppard, B. C. Chen, M. S. Haque, J. Ether Synthesis. The Journal of Organic Chemistry 2012, 77 (1) , 351-356. :: E1: First Gen Chem and Organic Chem: How are they different? This hemiaminal intermediate fragments to a sulfinimine and the desired α-hydroxy ketone. Learning New Reactions: How Do The Electrons Move?

How Gen Chem Relates to Organic Chem, Pt. Why Are Endo vs Exo Products Favored in the Diels-Alder Reaction?

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